Hi Naveen
Are you working on IS-Mill?
Message no is AD_SUBCON109 - Op. 0010 / 01 must have exactly one component as 'Rework Material to Subcontr.'?
Please implement OSS note 1288042 - Routing can not be saved in trx CA01 (error of note 1230619).
Also refer below link for same issue
Subcontracting for external operation routing in SAP Enhancement Package 4
Regards,
R.Brahmankar